South Africa lead the three-match series 1-0 after their easy win against Bangladesh on Sunday.
Quinton de Kock and Hashim Amla registered the highest opening stand by a South African pair.
Bangladesh are yet to beat South Africa in their own den.
Bangladesh will be itching to give it back to South Africa in the five ODIs after being demolished in the Test series.
The live streaming of the first ODI will be available in India on Sony LIV, while the live telecast will be available on Sony Six.
Rahman's participation in the ODI series also remains doubtful after the lanky left-armer picked up an ankle injury during training.
Bangladesh will hope for a turnaround in ODIs after being thrashed in the two-Test series against South Africa.
South Africa too have called in reinforcements in the form of AB de Villiers and JP Duminy.
South Africa are excepting a tougher challenge from Bangladesh in the three-match ODI series starting at Kimberley on Sunday.
Shakib Al Hasan top-scored with 68 but could not prevent a six-wicket defeat for the Bangladesh touring team against a South African Invitation XI.