The side under Paine became the first Australian side to have retained the Ashes on the English soil since 2001.
England won at The Oval by 135 runs in the fifth and final Ashes Test to tie the series at 2-2, ending their historic World Cup-winning season on a high.
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Victory for the home side means the Ashes ends in a draw for the first time since 1972, although holders Australia retain the urn.
Smith went past his own record of scoring 769 runs against India during the 2014-15 season.
At the tea interval on Day four Australia, who have already retained the Ashes, were 167-5.
If England manage to win the fifth and final Test, it would be the first drawn Ashes series since 1972.
David Warner's Ashes 2019 has finally ended with the Australian opener getting out to England veteran Stuart Broad for the seventh time.
Chappell also believed that sledging in the game should come to an end contrary to what others believe should be allowed to permissible limits.
England added 16 runs to their overnight score of 313 as Pat Cummins and Nathan Lyon dismissed Archer and Leach respectively to end England innings.